Improving Cyclability of Lithium Metal Anode via Constructing Atomic Interlamellar Ion Channel for Lithium Sulfur Battery

نویسندگان

چکیده

Abstract Uniform migration of lithium (Li) ions between the separator and anode is critical for achieving good quality Li deposition, which much significance metal battery operation, especially Li–sulfur (Li–S) batteries. Commercial separators such as polypropylene or polyethylene can be prepared by wet dry processes, but they indeed cause plentiful porosities, resulting in uneven ion stripping/plating finally formation dendrites. Thence, we constructed an atomic interlamellar channel introducing layered montmorillonite on surface to guide flux achieved stable deposition. The with a spacing 1.4 nm showed strong absorption capacity electrolytes reserved ions, thus promoting rapid transfer even deposition at anode. When assembled proposed separator, Coulombic efficiency Li||Cu batteries was 98.2% after 200 cycles plating/stripping 800 h Li||Li symmetric Importantly, allows 140% specific increase 190 employing Li–S

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ژورنال

عنوان ژورنال: Nanoscale Research Letters

سال: 2021

ISSN: ['1556-276X', '1931-7573']

DOI: https://doi.org/10.1186/s11671-021-03508-z